Task5. Work Function Difference (Calculate the work function difference assuming a gold (Au) gate.)

 

The work function ФM is defined as the minimum energy required for an electron with an energy equal to Fermi level to escape from the metal into vacuum. It is shown in figure 2.

For metals, the work functionФM=ФVA-ФFM is constant. Thus, ФM(Au)=5.1eV.

For semiconductors, the work function is:


which is shown in figure 2. According to known conditions, the electron affinity of Si is


and the Bandgap energy of silicon is


The Fermi potential ФF is equal to

and
is about 25mV at 300k.

Thus, Fermi potential:


and the work function of semiconductors:


The definition of Mental-Semiconductors work function difference is:

Thus, the work function difference:

Figure 2: Energy band diagram explaining work function


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